山中研究室

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K. Otsuka, I. Yamanaka,
Oxygenation of Alkanes and Aromatics by Reductively Activated Oxygen during H₂-O₂ Cell Reactions,
Catal. Today, 57, 71-86 (2000).

I. Yamanaka, M. Soma and K. Otsuka,
Partial Oxidation of Light Alkanes by Reductively Activated Oxygen in Eu-Catalytic System at 40℃,
Res. Chem. Intermed., 26, 129-135 (2000).

I. Yamanaka, M. Katagiri, S Takenaka and K. Otsuka,
Direct Synthesis of Phenol from Benzene with O₂ over VMo-Oxide/SiO₂ Catalyst,
Stud. Surf. Sci. & Catal., 130, 809-814 (2000).

I. Yamanaka, T Nabeta, S Takenaka and K. Otsuka,
Eu-Ti-Pt-Catalytic System for Direct Hydroxylation of Benzene by O₂ and H₂ under Mild Conditions,
Stud. Surf. Sci. & Catal., 130, 815-820 (2000).

I. Yamanaka, T. Furukawa and K. Otsuka,
Oxidation of Alkanes with H₂O on Ir(acac)₃ Supported on a Carbon Fiber-Anode,
Chem. Commun., 2209-2210 (2000).

M. Nakamura, S Takenaka, I. Yamanaka and K. Otsuka,
Production of Alkenes through Oxidative Cracking of n-Butane over OCM Catalysts,
Stud. Surf. Sci. & Catal., 130, 1781-1786 (2000).

プロトンと電子の流 れが生み出す新規触媒反応システム, 山中一郎, 大塚　潔,
化学工業, 51, 23-26 (2000).

K. Otsuka, R. Takahashi and I. Yamanaka,
Oxygenates from Light Alkanes Catalyzed by NO_x in the Gas Phase,
J. Catal., 185, 182-191 (1999).

I. Yamanaka, K. Sato and K. Otsuka
Electrolytic Synthesis of Propene Oxide from Propene and Water in the Gas Phase,
Electrochem. & Sol. St. Lett., 2, 131-132 (1999).

I. Yamanaka, M. Soma and K. Otsuka,
Oxidation of Methane to Methanol with O₂ Catalyzed by the Europium System under Mild Conditions,
Kinet. & Catal., 40, 414-417 (1999).

A. I. Tsyganok, I. Yamanaka and K. Otsuka,
Dechlorination of Chloroaromatics by Electrocatalytic Reduction over Palladium-Loaded Carbon Felt at Room Temperature,
Chemosphere, 39, 1819-1831 (1999).

窒素酸化物を用いた 酸化反応, 大塚　潔, 山中一郎,
触媒, 41, 606-611 (1999).

K. Otsuka, I. Yamanaka, and Y. Wang
Reductive Activation of Oxygen for Partial Oxidation of Light Alkanes,
Stud. Surf. Sci. & Catal., 119, 15-24 (1998).

K. Otsuka, N. Nakajima, and I. Yamanaka
Decomposition and Regeneration of Methane by Hydrogen Absorbing Alloys,
Chem. Lett., 873-874 (1998).

K. Otsuka, R. Takahashi, A. and I. Yamanaka
Partial Oxidation of Light Alkanes by NO_x in the gas phase,
Catal. Today, 45, 23-28 (1998).

K. Otsuka and I. Yamanaka
Electrochemical Cells as Reactors for Selective Oxygenation of Hydrocarbons at Low Temperature,
Catal. Today, 41, 311 (1998).

K. Otsuka, Y. Wang, E. Sunada, T. Ushiyama, and I. Yamanaka
Direct Partial Oxidation of Methane to Synthesis Gas by Cerium Oxide,
J. Catal., 175, 152-160 (1998).

I. Yamanaka, A. Nishi, and K. Otsuka
Selective Synthesis of MeCHO by C₂H₄-(O₂+NO) Cell System,
Chem. Commun., 2105-2106 (1998).

I. Yamanaka, T. Furukawa, and K. Otsuka
Oxidation of Benzene to Benzoquinone during Electrolysis of Water over the Carbon Fiber-Anode,
Chem. Lett., 1059-1060 (1998).

I. Yamanaka, K. Morimoto, M. Soma, and K. Otsuka
Oxidation of Methane and benzene with oxygen catalysed by reduced vanadium species at 40^oC,
J. Mol. Catal. A, 133, 251 (1998).

I. Yamanaka, K. Nakagaki, and K. Otsuka
One-Step Synthesis of Propylene Oxide Catalysed by the EuCl₃-O₂-Zn-MeCO₂H-System,
Appl. Catal. A, 171, 309 (1998).

A. I. Tsyganok, I. Yamanaka, and K. Otsuka
Pd-Loaded Carbon Felt as the Cathode for Selective Dechlorination of 2,4-Dichlorophenoxyacetic Acid in Aqueous Solution,
J. Electrochem. Soc., 145, 3844-3850 (1998).

A. I. Tsyganok, I. Yamanaka, and K. Otsuka
Electrocatalytic Dehalogenation of Chloroaromatics on Palladium-loaded Carbon Felt Cathode in Aqueous Medium,
Chem. Lett., 303 (1998).

K. Otsuka, E. Sunada, T. Ushiyama, and I. Yamanaka
The Production of Synthesis Gas by the Gas by the Redox of Cerium Oxide,
Stud. Surf. Sci. & Catal., 107, 531 (1997).

K. Otsuka, T. Ando, and I. Yamanaka
Hydroformylation of Ethylene via Spontaneous Cell reactions in the Gas Phase,
J. Catal., 165, 221 (1997).

ケミカルズ・電力‐ コジェネレーション型燃料電池‐, 大塚潔，山中一郎
化学と工業, 50, 1327-1328 (1997).

K. Otsuka, Q. Zhang, I. Yamanaka, H. Tono, M. Hatano, and H. Kinoshita
Reaction Mechanism of NO Reduction by CH₄ over Rare Earth Oxides in Oxidizing Atmosphere,
Bull. Chem. Soc. Jpn., 69, 3367 (1996).

K. Otsuka, H. Sawada, and I. Yamanaka
A Hydrogen-Nitric Oxide Cell for the Synthesis of Hydroxylamine,
J. Electrochem. Soc., 143, 3491 (1996).

I. Yamanaka, M. Soma, and K. Otsuka
Enhancing Effect of Titanium(II) for the Oxidation of Methane with O₂ by an EuCl₃-Zn-CF₃CO₂H-Catalytic System at 40^oC,
Chem. Lett., 565 (1996).

I. Yamanaka, K. Nakagaki, T. Akimoto, and K. Otsuka
Reactivity of Active Oxygen Species Generated in the EuCl₃
J. Chem. Soc., Perkin Trans. 2, 2511 (1996).

I. Yamanaka, T. Akimoto, K. Nakagaki, and K. Otsuka
Oxidation and Epoxidation of Hydrocarbons with O₂₃,
J. Mol. Catal. A, 110, 119 (1996).

A. Tsyganok, K. Otsuka, I. Yamanaka, V. Plekhanov, and S. Kulikov
Selective Electrochemical Dehalogenation of 2,4-Dichlorophenoxyacetic Acid in MeCN at Room temperature,
Chem. Lett., 261 (1996).

K. Otsuka, T. Ushiyama, I. Yamanaka, and K. Ebitani
Electrocatalytic Synthesis of Propylene Oxide during Water Electrolysis,
J. Catal., 157, 450 (1995).

K. Otsuka, T. Yagi and I. Yamanaka
Electrolytic Carbonylation of Methanol over the CuCl₂ Anode in the Gas Phase,
J. Electrochem. Soc., 142, 130 (1995).

K. Otsuka, T. Ando, S. Suprapto, Y. Wang, K. Ebitani, and I. Yamanaka
Ethane Oxidative Dehydrogenation over Boron Oxides Supported on Yttria Stabilized Zirconia,
Catal. Today, 24, 315 (1995).

I. Yamanaka, M. Soma and K. Otsuka
Oxidation of Methane to Methanol with Oxygen Catalysed by Europium trichloride at Room Temperature,
J. Chem. Soc., Chem. Commun., 2235 (1995).

I. Yamanaka, K. Nakagaki and K. Otsuka
Direct Synthesis of Propene Oxide by Using a EuCl₃-catalytic System at Room Temperature,
J. Chem. Soc., Chem. Commun., 1185 (1995).

I. Yamanaka and K. Otsuka
Catalysis of Sm³⁺ for the Oxidation of Alkanes with O₂ in the Liquid Phase,
J. Mol. Catal. A, 95, 115 (1995).

K. Otsuka, I. Yamanaka and M. Hagiwara
Simultaneous Epoxidation of 1-Hexene and Hydroxylation of Benzene during Electrolysis of Water,
Chem. Lett., 1861 (1994).

K. Otsuka, T. Yagi and I. Yamanaka
Dimethyl Carbonate Synthesis by Electrolytic Carbonylation of Methanol in the Gas Phase,
Electrochim. Acta, 39, 2109 (1994).

K. Otsuka, M. Kunieda and I. Yamanaka
Partial Oxidation of Benzene over the Carbon Whisker Cathode Added with Iron Oxide and Palladium Black during O₂-H₂ Fuel Cell Reactions,
Stud. Surf. Sci. & Catal., 82, 703 (1994).

K. Otsuka, Y. Wang, I. Yamanaka, A. Morikawa and M. Y. Sinev
Partial Oxidation of Methane over Iron Molybdate Catalyst,
Stud. Surf. Sci. & Catal., 81, 503 (1994).

K. Otsuka, T. Yagi and I. Yamanaka
Synthesis of Dimethyl Carbonate by Electrolytic Carbonylation of Methanol in the Gas Phase,
Chem. Lett., 495 (1994).

K. Otsuka, T. Ando, and I. Yamanaka
Oxidative Dehydrogenation of Ethane over B₂O₃ Catalysts Supported on Yttria Stabilized Zirconia,
Trans. Mat. Res. Soc. Jpn., 15A, 91-94 (1994).

I. Yamanaka, T. Akimoto and K. Otsuka
Gas Phase Oxidation of Benzene to Phenol and Hydroquinone by Using an H₂-O₂ Fuel Cell System,
Electrochim. Acta, 39, 2545 (1994).

I. Yamanaka, K. Nakagaki, T. Akimoto and K. Otsuka
Epoxidation of alkenes with O₂ catalyzed by EuCl₃ under ambient conditions,
Chem. Lett., 1717 (1994).

I. Yamanaka, T. Akimoto and K. Otsuka
Europium-catalysis for the mono-oxygenation of alkanes in the liquid phase,
Chem. Lett., 1511 (1994).

I. Yamanaka and K. Otsuka
Investigation of the nature of active oxygen intermediate at graphite-supported SmCl₃ and FeCl₃ working as a cathode for the partial oxidation of alkanes and aromatics,
J. Chem. Soc. Faraday Trans., 90, 451 (1994).

Catalytic System for Monooxygenation of Hydrocarbons Catalysed by EuCl 電池を応用した合成反応, 大塚潔, 山中一郎
表面, 32, 152 (1994).

K. Otsuka, Y. Wang, I. Yamanaka and A. Morikawa
Kinetic Study of the Partial Oxidation of Methane over Fe₂(MoO₄)₃ Catalyst,
J. Chem. Soc., Faraday Trans., 89, 4225 (1993).

K. Otsuka, T. Ushiyama and I. Yamanaka
Partial Oxidation of Methane Using the Redox of Cerium Oxide,
Chem. Lett., 1517 (1993).

K. Otsuka, M. Yoshinaka and I. Yamanaka
Epoxidation of Cyclohexene with the Nascent Oxygen generated by Electrolysis of Water,
J. Chem. Soc., Chem. Commun., 611 (1993).

I. Yamanaka and K. Otsuka
Cyclohexane Oxidation with Dioxygen Catalyzed by Samarium (III),
J. Mol. Catal., 83, L15 (1993).

I. Yamanaka and K. Otsuka
Partial Oxidation of Cyclohexane with Reductively Activated Dioxygen on SmCl₃ supported on Graphite during H₂-O₂ Fuel Cell Reactions,
J. Chem. Soc., Faraday Trans., 89, 1791 (1993).

I. Yamanaka and K. Otsuka
Partial oxidation of alkanes and aromatics with activated oxygen over an SmCl₃-embedded graphite cathode,
Alloys & Comp., 193, 56 (1993).

K. Otsuka, K. Ishizuka and I. Yamanaka
Synthesis of Cresol by Applying H₂-O₂ Fuel Cell Reaction,
Electrochim. Acta, 37, 2549 (1992).

K. Otsuka, K. Ishizuka and I. Yamanaka
Partial Oxidation of Toluene to Benzaldehyde and Benzyl Alcohol by Applying an H₂-O₂ Fuel Cell System,
Chem. Lett., 773 (1992).

K. Otsuka, K. Ishizuka, I. Yamanaka and M. Hatano
The Selective Oxidation of Toluene to Benzaldehyde Applying a Fuel Cell System in the Gas Phase,
J. Electrochem. Soc., 138, 3176 (1991).

K. Otsuka and I. Yamanaka
The Partial Oxidation of Cyclohexane by Activated Oxygen during the Fuel Cell Reactions of O₂ and H₂,
Catal. Sci. Techn., 1, 231 (1991).

I. Yamanaka and K. Otsuka
The Partial Oxidation of Cyclohexane and Benzene on the FeCl₃-Embedded Cathode during the O₂-H₂ Fuel cell reactions,
J. Electrochem. Soc., 138, 1033 (1991).

K. Otsuka, I. Yamanaka and K. Hosokawa
A Fuel Cell for the Partial Oxidation of Cyclohexane and Aromatics at Ambient Temperature,
Nature (London), 345, 698 (1990).

K. Otsuka and I. Yamanaka
The Partial Oxidation of Benzene and Cyclohexane During Fuel Cell Reactions of O₂ and H₂,
Chem. Lett., 509 (1990).

K. Otsuka, Y. Shimizu and I. Yamanaka
Selective Synthesis of Acetaldehyde Applying a Fuel Cell System in the Gas Phase,
J. Electrochem. Soc., 137, 2076 (1990).

K. Otsuka, K. Suga and I. Yamanaka
Oxidative Coupling of Methane Applying a Solid Oxide Fuel Cell,
Catal. Today, 6, 587 (1990).

K. Otsuka and I. Yamanaka
One Step Synthesis of Hydrogen Peroxide through Fuel Cell Reaction,
Electrochim. Acta, 35, 319 (1990).

K. Otsuka, K. Hosokawa, I. Yamanaka, Y. Wada and A. Morikawa
One-step Oxidation of Benzene to Phenol Applying a Fuel Cell System,
Electrochim. Acta, 34, 1485 (1990).

K. Otsuka, Y. Shimizu, I. Yamanaka and T. Komatsu
Wacker Type and π-Allyl Type Oxidations of Propylene Controlled by Fuel Cell System in the Gas Phase,
Catal. Lett., 3, 365 (1989).

I. Yamanaka and K. Otsuka
The electrochemical Promoted Formations of Formaldehyde And Dimethyl Ether During Electrochemical Oxidation of Methanol and Methylal,
Electrochim. Acta, 34, 211 (1989).

プロトン伝導触媒に よる反応, 大塚潔, 山中一郎
表面, 27, 473 (1989).

K. Otsuka, K. Suga and I. Yamanaka
Electrochemical Enhancement of Oxidative Coupling of Methane over LiCl-Doped NiO Using Stabilized Zirconia Electrolyte
Catal. Lett., 1, 423 (1988).

K. Otsuka, Y. Shimizu and I. Yamanaka
Selective Synthesis of Acetaldehyde using a Fuel Cell System in the Gas Phase,
J. Chem. Soc., Chem. Commun., 1272 (1988).

K. Otsuka, K. Suga and I. Yamanaka
Electrochemical Control for Oxidative Coupling of Methane over LiNiO₂ Using Solid Electrolytes,
Chem. Lett., 317 (1988).

I. Yamanaka and K. Otsuka
Partial Oxidation of Methanol Using a Fuel Cell System at Room Temperature,
Chem. Lett., 753 (1988).

K. Otsuka and I. Yamanaka
The Active Hydrogen Electrochemically or Thermally Generated on Pd/H₃PO₄/Pd catalysts,
Chem. Lett., 1945 (1987).

K. Otsuka, I. Yamanaka and K. Suga
Synthesis of Methyl Formate by Electrocatalytic Oxidation of Methanol in the Gas Phase Using Heteropoly and Phosphoric Acids,
Chem. Lett., 1087 (1987).

K. Otsuka and I. Yamanaka
Electrocatalytic Synthesis of Methyl Formate and Methylal from Methanol on a Platinum-bonded Solid Polymer Electrolyte Membrane,
Appl. Catal., 26, 401 (1986).

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